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Controlling the aggregation and assembly of boron-containing molecular and polymeric materials
Aggregate ( IF 13.9 ) Pub Date : 2022-01-20 , DOI: 10.1002/agt2.149 Daisuke Shimoyama 1 , Frieder Jäkle 1
Aggregate ( IF 13.9 ) Pub Date : 2022-01-20 , DOI: 10.1002/agt2.149 Daisuke Shimoyama 1 , Frieder Jäkle 1
Affiliation
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Boron-containing molecules and polymers are attractive as powerful tunable Lewis acids for small molecule activation and catalysis, as luminescent materials for organic electronic device and (bio)imaging applications, and as smart chemical sensors. While the characteristics of the boron-containing building blocks are attractive in and of themselves, their assembly into higher order supramolecular materials offers access to unique properties and emerging functions. Herein, we highlight recent achievements in the field of aggregated organoboron materials. We discuss how supramolecular interactions can be exploited to precisely control the structure of the assemblies and impact their functions as luminescent materials, recyclable and smart catalyst systems, chemical sensors, stimuli-responsive and self-healing materials.
中文翻译：
控制含硼分子和聚合物材料的聚集和组装
含硼分子和聚合物作为用于小分子活化和催化的强大可调谐路易斯酸、作为有机电子设备和（生物）成像应用的发光材料以及作为智能化学传感器具有吸引力。虽然含硼结构单元的特性本身很有吸引力，但它们组装成更高阶的超分子材料提供了获得独特性能和新兴功能的途径。进来，我们重点介绍一下聚合有机硼材料领域的最新成就。我们讨论了如何利用超分子相互作用来精确控制组件的结构并影响它们作为发光材料、可回收和智能催化剂系统、化学传感器、刺激响应和自愈材料的功能。
更新日期：2022-01-20
中文翻译：
控制含硼分子和聚合物材料的聚集和组装
含硼分子和聚合物作为用于小分子活化和催化的强大可调谐路易斯酸、作为有机电子设备和（生物）成像应用的发光材料以及作为智能化学传感器具有吸引力。虽然含硼结构单元的特性本身很有吸引力，但它们组装成更高阶的超分子材料提供了获得独特性能和新兴功能的途径。进来，我们重点介绍一下聚合有机硼材料领域的最新成就。我们讨论了如何利用超分子相互作用来精确控制组件的结构并影响它们作为发光材料、可回收和智能催化剂系统、化学传感器、刺激响应和自愈材料的功能。
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