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Convenient preparative approaches to biorelevant dimethylphosphinoyl-derived compounds with the use of (trimethylsilyl)dimethylphosphinite
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2022-01-20 , DOI: 10.1080/10426507.2021.2025054 Anastasiia M. Aleksandrova 1 , Ludmyla V. Bezgubenko 1 , Alona S. Cherednichenko 1 , Petro P. Onys’ko 1 , Yuliya V. Rassukana 1, 2
中文翻译：
使用（三甲基甲硅烷基）二甲基亚膦酸酯制备生物相关二甲基膦酰基衍生化合物的便捷制备方法
更新日期：2022-01-20
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2022-01-20 , DOI: 10.1080/10426507.2021.2025054 Anastasiia M. Aleksandrova 1 , Ludmyla V. Bezgubenko 1 , Alona S. Cherednichenko 1 , Petro P. Onys’ko 1 , Yuliya V. Rassukana 1, 2
Affiliation
Abstract
A convenient procedure for the preparation of (trimethylsilyl)dimethylphosphinite was developed. The synthetic potential of the latter was exemplified by the preparation of dimethylphosphinoyl-derived nitriles, amines, acetone, acetic and acetoacetic acids as valuable building blocks for medicinal and materials chemistry.
中文翻译：
使用（三甲基甲硅烷基）二甲基亚膦酸酯制备生物相关二甲基膦酰基衍生化合物的便捷制备方法
摘要
开发了一种方便的制备（三甲基甲硅烷基）二甲基亚膦酸酯的方法。后者的合成潜力通过制备二甲基膦酰基衍生的腈、胺、丙酮、乙酸和乙酰乙酸作为药物和材料化学的重要组成部分来例证。
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