Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes,Angewandte Chemie International Edition

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Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-01-10 , DOI: 10.1002/anie.202115497
Youliang He ₁ , Yuxiao Wang ₁ , Shi-Jun Li ₂ , Yu Lan _{2,

3} , Xiaoming Wang _{1,

4}

Affiliation

An attractive deoxygenative cross-coupling of amides with polyfluoroarenes was successfully achieved. Aromatic amides act as readily available carbene precursors through a Sm/SmI₂-mediated deoxygenation process, and the insertion of the carbene into the C−H bond of polyfluoroarene affords architecturally complex and functionally diverse α-polyfluoroaryl amines in a single step.

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