Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.3 ) Pub Date : 2021-12-30 , DOI: 10.1016/j.saa.2021.120827 Boeon Suh 1 , Hyeongjin Kim 1 , Soogyeong Jang 2 , Ki-Tae Kim 2 , Cheal Kim 1
![]() |
A benzothiazole-based fluorescent and colorimetric chemosensor BZD ((E)-2-(benzo[d]thiazol-2-yl)-5-((4-(diethylamino)-2-hydroxybenzylidene)amino)phenol) was applied for detecting ClO−. BZD showed fluorescence quenching and color variation for ClO− via oxidative reaction between ClO− and the imine bond. It could effectively detect ClO− over various competitive analytes. Detection limit for ClO− was calculated to be 1.74 μM by fluorescent method and 16.44 μM by colorimetric one, respectively. Additionally, BZD could be utilized for sensing ClO− in zebrafish, real water sample and paper strip. The photophysical characteristics and sensing mechanism of BZD to ClO− were studied by fluorescent and UV–visible spectroscopy, NMR titration, and ESI-mass spectrometry.
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
一种基于苯并噻唑的荧光比色探针检测二氧化氯-及其在斑马鱼和水样中的应用
一种基于苯并噻唑的荧光比色化学传感器BZD ((E)-2-(benzo[d]thiazol-2-yl)-5-((4-(diethylamino)-2-hydroxybenzylidene)amino)phenol) 用于检测二氧化氯-。BZD通过 ClO -和亚胺键之间的氧化反应显示了 ClO -的荧光猝灭和颜色变化。它可以有效地检测 ClO -超过各种竞争性分析物。ClO -的检测限通过荧光法计算为 1.74 μM,通过比色法计算为 16.44 μM。此外,BZD可用于感测 ClO -在斑马鱼、真实水样和纸条中。通过荧光和紫外-可见光谱、核磁共振滴定和 ESI 质谱研究了BZD对 ClO -的光物理特性和传感机制。