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A benzothiazole-based fluorescent and colorimetric probe for the detection of ClO− and its application to zebrafish and water sample
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.3 ) Pub Date : 2021-12-30 , DOI: 10.1016/j.saa.2021.120827
Boeon Suh 1 , Hyeongjin Kim 1 , Soogyeong Jang 2 , Ki-Tae Kim 2 , Cheal Kim 1
Affiliation  

A benzothiazole-based fluorescent and colorimetric chemosensor BZD ((E)-2-(benzo[d]thiazol-2-yl)-5-((4-(diethylamino)-2-hydroxybenzylidene)amino)phenol) was applied for detecting ClO. BZD showed fluorescence quenching and color variation for ClO via oxidative reaction between ClO and the imine bond. It could effectively detect ClO over various competitive analytes. Detection limit for ClO was calculated to be 1.74 μM by fluorescent method and 16.44 μM by colorimetric one, respectively. Additionally, BZD could be utilized for sensing ClO in zebrafish, real water sample and paper strip. The photophysical characteristics and sensing mechanism of BZD to ClO were studied by fluorescent and UV–visible spectroscopy, NMR titration, and ESI-mass spectrometry.



中文翻译:

一种基于苯并噻唑的荧光比色探针检测二氧化氯-及其在斑马鱼和水样中的应用

一种基于苯并噻唑的荧光比色化学传感器BZD ((E)-2-(benzo[d]thiazol-2-yl)-5-((4-(diethylamino)-2-hydroxybenzylidene)amino)phenol) 用于检测二氧化氯-BZD通过 ClO -和亚胺键之间的氧化反应显示了 ClO -的荧光猝灭和颜色变化。它可以有效地检测 ClO -超过各种竞争性分析物。ClO -的检测限通过荧光法计算为 1.74 μM,通过比色法计算为 16.44 μM。此外,BZD可用于感测 ClO -在斑马鱼、真实水样和纸条中。通过荧光和紫外-可见光谱、核磁共振滴定和 ESI 质谱研究了BZD对 ClO -的光物理特性和传感机制。

更新日期:2022-01-05
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