The bond-formation strategy associated with carbon and nitrogen atoms is one of the most vital fundamental techniques in the construction of organic molecules. In comparison to well-established methodologies of C–C and C–N bond formation in general synthetic chemistry, the development of N–N single bond formation for nitrogen-rich organic compounds is relatively rare. This paper summarizes the advances made in N-amination reagents and reaction conditions over the recent five years in terms of the N–N bond formation of high-energy frameworks, such as pyrazoles, 1,2,4-triazoles, 1,2,3-triazoles, and 1,3,4-oxadiazoles. Furthermore, this paper discusses the physiochemical properties of recent N-amino heterocyclic compounds and their energetic derivatives, thereby holding great promise as a guideline for rational structural modification of energetic materials. This work is aimed at providing an overall view of N-amination to access diversely functionalized energetic materials.

与碳和氮原子相关的键形成策略是构建有机分子的最重要的基础技术之一。与一般合成化学中成熟的 C-C 和 C-N 键形成方法相比，富氮有机化合物形成 N-N 单键的开发相对较少。本文从吡唑类、 1,2,4-三唑类、1,2、 3-三唑和1,3,4-恶二唑。此外，本文还讨论了最近N的理化性质。-氨基杂环化合物及其含能衍生物，因此有望作为含能材料合理结构改性的指南。这项工作旨在提供N-胺化的总体视图，以获取多种功能化的高能材料。