Corey−Chaykovsky Epoxidation of Twisted Amides: Synthesis and Reactivity of Bridged Spiro-epoxyamines,Journal of the American Chemical Society

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Corey−Chaykovsky Epoxidation of Twisted Amides: Synthesis and Reactivity of Bridged Spiro-epoxyamines
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2009-09-23 , DOI: 10.1021/ja906471q
Michal Szostak ₁ , Jeffrey Aubé

Affiliation

The first example of a Corey-Chaykovsky epoxidation employing amides as substrates is described. Medium-bridged twisted amides serve as precursors to a family of isolable aminoepoxides. The reactivity of bridged spiro-epoxyamines is also investigated.

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