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Two Giant Calixarene-Like Polyoxoniobate Nanocups {Cu12Nb120} and {Cd16Nb128} Built from Mixed Macrocyclic Cluster Motifs
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-12-17 , DOI: 10.1002/anie.202113381
Zeng-Kui Zhu 1 , Jing Zhang 1 , Yu-Chen Cong 1 , Rui Ge 1 , Zhong Li 1 , Xin-Xiong Li 1 , Shou-Tian Zheng 1
Affiliation  

Calixarene-like polyoxoniobates: Two unprecedented giant calixarene-like polyoxoniobate (PONb) nanocups based on multiple macrocyclic clusters have been made, showing the fusion of two areas of metallacalixarene and PONb chemistry. The two molecular nanocups are by far the largest two inorganic–organic hybrid PONbs and hold promise for developing largely unexplored inorganic–organic hybrid PONb chemistry.
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中文翻译:

由混合大环簇基序构建的两个巨大的类杯芳烃多氧铌酸盐纳米杯 {Cu12Nb120} 和 {Cd16Nb128}

类杯芳烃多氧铌酸盐:基于多个大环簇,制造了两种前所未有的巨型类杯芳烃多氧铌酸盐 (PONb) 纳米杯,展示了金属杯芳烃和 PONb 化学两个领域的融合。这两个分子纳米杯是迄今为止最大的两个无机-有机杂化 PONb,并且有望开发很大程度上尚未开发的无机-有机杂化 PONb 化学。
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更新日期:2022-02-01
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