A Non-Ionic Precursor for Preparing Di-, Tetra-, Hexanitro-2,4,6,8,10,12-hexaazatricyclo[7,3,0,03,7]dodecane-5,11-dione: Synthesis, Mechanism and Properties,ChemistrySelect

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A Non-Ionic Precursor for Preparing Di-, Tetra-, Hexanitro-2,4,6,8,10,12-hexaazatricyclo[7,3,0,03,7]dodecane-5,11-dione: Synthesis, Mechanism and Properties
ChemistrySelect ( IF 1.9 ) Pub Date : 2021-12-02 , DOI: 10.1002/slct.202103676
Xiya Zhang ₁ , Xiangyang Lin ₁ , Haifeng Huang ₂

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A non-ionic precursor 2,4,6,8,10,12-hexaazatricyclo[7,3,0,0^3,7]dodecane-5,11-dione (HTDD) is designed and applied to synthesize 2,4,6,8,10,12-hexaazatricyclo[7,3,0,0^3,7]dodecane-5,11-dione (HHTDD) and its derivatives. The non-ionic precursor has stronger electrophilic reactivity and is easier to react with NO₂⁺ compared to the ionic analogue, and the products can be obtained under moderate nitration condition.

中文翻译：

一种用于制备二、四、六硝基-2,4,6,8,10,12-六氮杂三环[7,3,0,03,7]dodecane-5,11-dione 的非离子前体：合成、机理和属性

设计了一种非离子前驱体 2,4,6,8,10,12-六氮杂三环[7,3,0,0 ^3,7 ] dodecane -5,11-dione ( HTDD ) 并应用于合成 2,4, 6,8,10,12-六氮杂三环[7,3,0,0 ^3,7 ] dodecane -5,11-dione (HHTDD) 及其衍生物。与离子类似物相比，非离子前驱体具有更强的亲电反应性，更容易与NO ₂⁺反应，在中等硝化条件下可以得到产物。

更新日期：2021-12-03

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