批判性评论，最近更新沸石咪唑酯框架 67 (ZIF-67) 及其用于电化学水分解的衍生物,Advanced Materials

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批判性评论，最近更新沸石咪唑酯框架 67 (ZIF-67) 及其用于电化学水分解的衍生物
Advanced Materials ( IF 27.4 ) Pub Date : 2021-11-30 , DOI: 10.1002/adma.202107072
Harsharaj S Jadhav ₁ , Harshad A Bandal ₁ , Seeram Ramakrishna ₂ , Hern Kim ₁

Affiliation

设计和构建具有高催化活性和长期稳定性的低成本电催化剂是催化领域的一项艰巨任务。金属有机框架（MOF）作为前体材料在开发用于能量转换和存储应用的高效电催化剂方面是很有前途的候选者。本综述首先概述了电化学水分解反应中涉及的基本概念和关键评估参数。然后，对钴基沸石咪唑酯骨架 (ZIF-67) 及其衍生物的不同合成方法进行了严格审查。此外，还详细讨论了用于增强 ZIF-67 基电催化剂的电催化活性和稳定性的几种策略。本综述简要介绍了用于析氧的 ZIF-67 及其衍生物（氧化物、氢氧化物、硫化物、硒化物、磷化物、氮化物、碲化物、杂原子/金属掺杂碳、贵金属负载的 ZIF-67 衍生物）反应 (OER)、析氢反应 (HER) 和整体水分解应用。最后，本综述总结了相关挑战和开发最佳经济、耐用电催化材料的前景。

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Critical Review, Recent Updates on Zeolitic Imidazolate Framework-67 (ZIF-67) and Its Derivatives for Electrochemical Water Splitting

Design and construction of low-cost electrocatalysts with high catalytic activity and long-term stability is a challenging task in the field of catalysis. Metal-organic frameworks (MOF) are promising candidates as precursor materials in the development of highly efficient electrocatalysts for energy conversion and storage applications. This review starts with a summary of basic concepts and key evaluation parameters involved in the electrochemical water-splitting reaction. Then, different synthesis approaches reported for the cobalt-based Zeolitic imidazolate framework (ZIF-67) and its derivatives are critically reviewed. Additionally, several strategies employed to enhance the electrocatalytic activity and stability of ZIF-67-based electrocatalysts are discussed in detail. The present review provides a succinct insight into the ZIF-67 and its derivatives (oxides, hydroxides, sulfides, selenides, phosphide, nitrides, telluride, heteroatom/metal-doped carbon, noble metal-supported ZIF-67 derivatives) reported for oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and overall water splitting applications. Finally, this review concludes with the associated challenges and the perspectives on developing the best economic, durable electrocatalytic materials.

更新日期：2021-11-30

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