Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis,Chemical Reviews

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Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis
Chemical Reviews ( IF 51.4 ) Pub Date : 2021-11-29 , DOI: 10.1021/acs.chemrev.1c00603
Daniel A Corbin ₁ , Garret M Miyake ₁

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The development of photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP) has received considerable attention since its introduction in 2014. Expanding on many of the advantages of traditional ATRP, O-ATRP allows well-defined polymers to be produced under mild reaction conditions using organic photoredox catalysts. As a result, O-ATRP has opened access to a range of sensitive applications where the use of a metal catalyst could be of concern, such as electronics, certain biological applications, and the polymerization of coordinating monomers. However, key limitations of this method remain and necessitate further investigation to continue the development of this field. As such, this review details the achievements made to-date as well as future research directions that will continue to expand the capabilities and application landscape of O-ATRP.

中文翻译：

光诱导有机催化原子转移自由基聚合 (O-ATRP)：使用有机光氧化还原催化的精密聚合物合成

自 2014 年推出以来，光诱导有机催化原子转移自由基聚合 (O-ATRP) 的发展受到了相当大的关注。O-ATRP 扩展了传统 ATRP 的许多优点，允许在温和的反应条件下使用有机光氧化还原催化剂。因此，O-ATRP 已经打开了一系列敏感应用的大门，在这些应用中，金属催化剂的使用可能会受到关注，例如电子、某些生物应用和配位单体的聚合。然而，这种方法的主要局限性仍然存在，需要进一步调查以继续该领域的发展。因此，

更新日期：2022-01-26

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