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Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2021-11-24 , DOI: 10.1002/asia.202101115
Ravi Kumar 1 , Fateh V Singh 2 , Naoko Takenaga 3 , Toshifumi Dohi 4
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This review summarizes hypervalent iodine-mediated oxidative dearomatization reactions of phenol and its derivatives that end up with enantioriched products. Oxidative dearomatization of phenolic compounds using chiral hypervalent iodine compounds as well as oxidative transformations involving hypervalent iodine followed by desymmetrization using chiral auxiliary are presented herein.
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中文翻译:

涉及高价碘试剂的不对称直接/逐步脱芳构化反应

本综述总结了高价碘介导的苯酚及其衍生物的氧化脱芳构化反应,最终得到对映体产物。本文介绍了使用手性高价碘化合物对酚类化合物进行氧化脱芳构化,以及涉及高价碘的氧化转化,然后使用手性助剂进行去对称化。
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更新日期:2021-11-24
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