Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen,Angewandte Chemie International Edition

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Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-11-19 , DOI: 10.1002/anie.202114191
Matteo Ceppatelli _{1,

2} , Demetrio Scelta _{1,

2} , Manuel Serrano-Ruiz ₂ , Kamil Dziubek _{1,

2} , Marta Morana ₃ , Volodymyr Svitlyk ₄ , Gaston Garbarino ₄ , Tomasz Poręba ₄ , Mohamed Mezouar ₄ , Maurizio Peruzzini ₂ , Roberto Bini _{1,

2,

5}

Affiliation

Cubic arsenic nitride was synthesized from arsenic and nitrogen under high-pressure and high-temperature conditions using a laser heated diamond anvil cell. The crystalline structure of AsN (P2₁3), in which every As atom is single-bonded to three N atoms and vice versa, was determined by synchrotron X-ray diffraction. The discovery of AsN is relevant to the fundamental chemistry of pnictogens and to synthesis of new advanced materials.

中文翻译：

砷和氮的高压高温化学反应生成单键立方 AsN

使用激光加热金刚石砧池在高压和高温条件下由砷和氮合成立方氮化砷。 AsN ( P 2 ₁ 3) 的晶体结构是通过同步加速器 X 射线衍射确定的，其中每个 As 原子与三个 N 原子单键结合，反之亦然。 AsN 的发现与氮元素的基础化学和新的先进材料的合成有关。

更新日期：2022-01-25

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