Cu(I)-Catalyzed Carboxylation of Aryl Boronic Acid with CO2,ChemistrySelect

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Cu(I)-Catalyzed Carboxylation of Aryl Boronic Acid with CO2
ChemistrySelect ( IF 1.9 ) Pub Date : 2021-11-16 , DOI: 10.1002/slct.202102980
Rong Zhou ₁ , MiLi Yang ₁ , YuQin Li ₁ , DingBang Li ₁

Affiliation

Carbon dioxide (CO₂) is one of the main greenhouse gases. The realization of the chemical conversion of CO₂ was significantly for green chemistry and sustainable development of economy. This work presented the reaction of arylboronic acids with CO₂ to achieve the formation of aryl carboxylic acids by using the inexpensive CuCl as a catalyst, 1,10-phenanthroline as the ligand, CH₃OK as the base and DMSO as the solvent. It was found that the system is of a wide tolerance of functional groups and the substrates bearing both electron-withdrawing and electron-donating groups could give corresponding carboxylic acids in the moderate to good yields.

中文翻译：

Cu(I)-催化芳基硼酸与 CO2 的羧化

二氧化碳（CO ₂）是主要的温室气体之一。CO ₂化学转化的实现对绿色化学和经济的可持续发展具有重要意义。这项工作介绍了芳基硼酸与 CO ₂的反应，通过使用廉价的 CuCl 作为催化剂、1,10-菲咯啉作为配体、CH ₃ OK 作为碱和 DMSO 作为溶剂来实现芳基羧酸的形成。发现该体系对官能团具有广泛的耐受性，同时带有吸电子基团和给电子基团的底物可以以中等至良好的产率得到相应的羧酸。

更新日期：2021-11-16

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