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Pd/Gorlos-Phos-Catalyzed Chemoselective Amination of Bromophenyl Chlorides with Primary Arylamines
Helvetica Chimica Acta ( IF 1.5 ) Pub Date : 2021-11-04 , DOI: 10.1002/hlca.202100173 Xinyu Duan 1 , Yulong Song 2 , Chunling Fu 1 , Shengming Ma 3
Helvetica Chimica Acta ( IF 1.5 ) Pub Date : 2021-11-04 , DOI: 10.1002/hlca.202100173 Xinyu Duan 1 , Yulong Song 2 , Chunling Fu 1 , Shengming Ma 3
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With the readily available Gorlos-Phos as a ligand, halogenated diarylamines were prepared efficiently from Pd-catalyzed monoamination of bromophenyl chlorides and primary arylamines, tolerating functional groups such as aldehyde, ketone, nitrile, fluorine, sulphonyl and trifluoromethyl groups. The formation of the amination of the C−Cl bond and diamination products were not observed.
中文翻译：
Pd/Gorlos-Phos 催化溴苯氯与伯芳胺的化学选择性胺化
使用容易获得的 Gorlos-Phos 作为配体，卤代二芳基胺由 Pd 催化的溴苯氯和伯芳基胺的单胺化有效地制备，可耐受醛、酮、腈、氟、磺酰基和三氟甲基等官能团。没有观察到 C-Cl 键的胺化和二胺化产物的形成。
更新日期：2021-11-04
中文翻译：
Pd/Gorlos-Phos 催化溴苯氯与伯芳胺的化学选择性胺化
使用容易获得的 Gorlos-Phos 作为配体，卤代二芳基胺由 Pd 催化的溴苯氯和伯芳基胺的单胺化有效地制备，可耐受醛、酮、腈、氟、磺酰基和三氟甲基等官能团。没有观察到 C-Cl 键的胺化和二胺化产物的形成。
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