Advances in Colloid and Interface Science ( IF 15.9 ) Pub Date : 2021-11-03 , DOI: 10.1016/j.cis.2021.102562
Wei Yin 1 , Guangxun Zhang 1 , Xinlan Wang 1 , Huan Pang 1
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Metal-organic frameworks (MOFs) are as a category of crystalline porous materials. Extensive interest has been devoted to energy storage and energy conversion applications owing to their unique advantages of periodic architecture, high specific surface area, high adsorption, high conductivity, high specific capacitance, and high porosity. One-dimensional (1D) nanostructures have unique surface effects, easily regulated size, good agglutination of the substrate, and other distinct properties amenable to the field of energy storage and conversion. Therefore, 1D nanostructures could further improve the characteristic properties of MOFs, and it is of great importance for practical applications to control the size and morphological characteristics of MOFs. The electrochemical application of 1D MOFs is mainly discussed in this review, including energy storage applications in supercapacitors and batteries and energy conversion applications in catalysis. In addition, various synthesis strategies for 1D MOFs and their architectures are presented.
中文翻译:

用于电化学应用的一维金属有机骨架
金属有机框架 (MOF) 是一类结晶多孔材料。由于其周期性结构、高比表面积、高吸附、高电导率、高比电容和高孔隙率的独特优势,人们对能量存储和能量转换应用产生了广泛的兴趣。一维 (1D) 纳米结构具有独特的表面效应、易于调节的尺寸、良好的基材粘合性以及其他适用于能量存储和转换领域的独特特性。因此,一维纳米结构可以进一步改善MOFs的特性,控制MOFs的尺寸和形态特征对实际应用具有重要意义。本综述主要讨论一维 MOF 的电化学应用,包括超级电容器和电池中的能量存储应用以及催化中的能量转换应用。此外,还介绍了 1D MOF 及其架构的各种合成策略。