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Nanoarchitectonics of the supercapacitor performance of LaNiO3 perovskite on the graphitic-C3N4 doped reduced graphene oxide hydrogel
Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 4.9 ) Pub Date : 2021-10-28 , DOI: 10.1016/j.colsurfa.2021.127787
Ersan HARPUTLU 1
Affiliation  

Designing highly efficient, low-cost hybrid nanostructures with having favorable morphology and excellent conductivity is very promising for electrodes used in electrochemical storage devices. This study shows the synthesis of a new three-dimensional (3D) hybrid structure consisting of lanthanum nickel oxide (LaNiO3) perovskite, graphite carbon nitride (g-C3N4), and reduced graphene oxide hydrogel (RGOH) structures for the new hybrid supercapacitor (SC) application. The 3D hybrid structure, which is a new SC application, draws attention according to the specific capacitance (Cs) result for graphene-based hydrogel structure. For this purpose, while g-C3N4 is selected to plays an important role to increase the electrochemical activity of SC, the LaNiO3 perovskite structure is used to increase the discharge capacity of SC as well as to provide high discharge current and long cycle life. As a result of electrochemical studies, the superior capacitive performance of LaFeO3/g-C3N4@RGOH showed Cs and unique performance of 750.56 F g−1 at a current density of 1 A g–1. The 3D structure is used as anode material for fabricating symmetric two-electrode supercapacitor systems. Moreover, the LaFeO3/g-C3N4@RGOH materials display magnificent cyclic stability of 82% for 5000 cycles at a current density of 10 A g − 1, which claims the new material progress in the energy field.



中文翻译:

LaNiO3钙钛矿在石墨-C3N4掺杂还原氧化石墨烯水凝胶上的超级电容器性能的纳米结构

设计具有良好形态和优异导电性的高效、低成本混合纳米结构对于用于电化学存储设备的电极非常有前景。本研究展示了由氧化镧镍 (LaNiO 3 ) 钙钛矿、石墨碳氮化物 (gC 3 N 4 ) 和还原氧化石墨烯水凝胶 (RGOH) 结构组成的新型三维 (3D) 杂化结构的合成,用于新杂化超级电容器 (SC) 应用。3D混合结构是一种新的SC应用,根据石墨烯基水凝胶结构的比电容(C s)结果引起了人们的注意。为此,虽然 gC 3 N 4LaNiO 3钙钛矿结构用于提高SC 的电化学活性,用于提高 SC 的放电容量以及提供高放电电流和长循环寿命。作为电化学研究的结果,LaFeO 3 /gC 3 N 4 @RGOH的优异电容性能在 1 A g –1的电流密度下显示出 C s和 750.56 F g -1 的独特性能。3D 结构用作制造对称双电极超级电容器系统的阳极材料。此外,LaFeO 3 /gC 3 N 4@RGOH 材料在 10 A g - 1的电流密度下在 5000 次循环中显示出 82% 的出色循环稳定性,这表明新材料在能源领域取得了进展。

更新日期:2021-11-07
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