共晶结晶激活固态锌离子传导
Angewandte Chemie International Edition
(
IF16.1
)
Pub Date : 2021-10-19, DOI: 10.1002/anie.202113086
Huayu Qiu
1,
2
,
Rongxiang Hu
1,
2
,
Xiaofan Du
2
,
Zhou Chen
2
,
Jingwen Zhao
2
,
Guoli Lu
2,
3
,
Meifang Jiang
2
,
Qingyu Kong
4
,
Yiyuan Yan
2
,
Junzhe Du
2
,
Xinhong Zhou
1
,
Guanglei Cui
2
Affiliation
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China.
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China.
School of Future Technology, University of Chinese Academy of Sciences, Beijing, 100190, China.
Société Civile Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin-BP 48, 91192, Gif-sur-Yvette Cedex, France.
Here, we discovered a novel crystallized Zn2+ conductor based on inducing crystallization of high-entropy, charge-separated eutectic liquids. To the best of our knowledge, it is the first introduction of the concept of a crystallized eutectic material to achieve dramatically enhanced multivalent-ion transport properties. This facile strategy may also open up opportunities for designing a wide variety of new solid ionic conductors.
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