Rhodium Indenyl NHC and Fluorenyl-Tethered NHC Half-Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C−H Borylation of Arenes and Alkanes,Chemistry - A European Journal

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Rhodium Indenyl NHC and Fluorenyl-Tethered NHC Half-Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C−H Borylation of Arenes and Alkanes
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2021-10-15 , DOI: 10.1002/chem.202102961
Kieren J. Evans ₁ , Paul A. Morton ₁ , Christian Luz ₁ , Callum Miller ₁ , Olivia Raine ₁ , Jason M. Lynam ₂ , Stephen Michael Mansell ₃

Affiliation

Indenyl rhodium NHC complexes with labile alkene ligands (ethene and cyclooctene) have been synthesized and shown to be better catalysts than the related fluorenyl-tethered NHC rhodium complexes for the C−H activation and borylation of arenes and alkanes.