Insight into Carbocation-Induced Noncovalent Interactions in the Methanol-to-Olefins Reaction over ZSM-5 Zeolite by Solid-State NMR Spectroscopy,Angewandte Chemie International Edition

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Insight into Carbocation-Induced Noncovalent Interactions in the Methanol-to-Olefins Reaction over ZSM-5 Zeolite by Solid-State NMR Spectroscopy
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-10-11 , DOI: 10.1002/anie.202112948
Chao Wang _{1,

2} , Yueying Chu _{1,

2} , Min Hu _{1,

2} , Wenjin Cai _{1,

2} , Qiang Wang _{1,

2} , Guodong Qi _{1,

2} , Shenhui Li _{1,

2} , Jun Xu _{1,

2} , Feng Deng _{1,

2}

Affiliation

Multiple noncovalent interactions involving cyclopentenyl cations in the methanol-to-olefins (MTO) reaction over ZSM-5 zeolite were identified by using two-dimensional solid-state NMR spectroscopy. It was found that the hydrocarbon pool reaction is modulated by carbocation-induced noncovalent interactions.