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CoFe-LDH nanowire arrays on graphite felt: A high-performance oxygen evolution electrocatalyst in alkaline media
Chinese Chemical Letters ( IF 9.4 ) Pub Date : 2021-10-07 , DOI: 10.1016/j.cclet.2021.10.002
Biao Deng 1 , Jie Liang 2 , Luchao Yue 2 , Tingshuai Li 2 , Qian Liu 3 , Yang Liu 4 , Shuyan Gao 4 , Abdulmohsen Ali Alshehri 5 , Khalid Ahmed Alzahrani 5 , Yonglan Luo 1 , Xuping Sun 2
Affiliation  

Developing non-noble-metal oxygen evolution reaction (OER) electrocatalysts with high performance is critical to electrocatalytic water splitting. In this work, we fabricated CoFe-layered double hydroxide (LDH) nanowire arrays on graphite felt (CoFe-LDH/GF) via a hydrothermal method. The CoFe-LDH/GF, as a robust integrated 3D OER anode, exhibits excellent catalytic activity with the need of low overpotential of 252 and 285 mV to drive current densities of 10 and 100 mA/cm2 in 1.0 mol/L KOH, respectively. In addition, it also maintains electrochemical durability for at least 24 h. This work would open up avenues for the development of GF like attractive catalyst supports for oxygen evolution applications.



中文翻译:

石墨毡上的 CoFe-LDH 纳米线阵列:碱性介质中的高性能析氧电催化剂

开发高性能的非贵金属析氧反应(OER)电催化剂对于电催化水分解至关重要。在这项工作中,我们通过水热法在石墨毡 (CoFe-LDH/GF) 上制造了 CoFe 层状双氢氧化物 (LDH) 纳米线阵列。CoFe-LDH/GF 作为坚固的集成 3D OER 阳极,表现出优异的催化活性,需要 252 和 285 mV 的低过电势才能在 1.0 mol/L KOH 中分别驱动 10 和 100 mA/cm 2的电流密度. 此外,它还能保持至少 24 小时的电化学耐久性。这项工作将为开发用于析氧应用的有吸引力的催化剂载体等 GF 开辟道路。

更新日期:2021-10-07
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