重新审视 MIL-101 金属有机框架：设计、合成、修改、进展和最近的应用,Journal of Materials Chemistry A

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重新审视 MIL-101 金属有机框架：设计、合成、修改、进展和最近的应用
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2021-09-25 , DOI: 10.1039/d1ta06238g
Mahmoud Y. Zorainy _{1,

2} , Mohamed Gar Alalm _{1,

3} , Serge Kaliaguine ₄ , Daria C. Boffito ₁

Affiliation

金属有机框架 (MOF) 已扩展为材料科学和工程领域的一个新兴话题。他们的成功主要源于其结构的多功能性，可以通过对组件的精确控制来进行多样化的设计。我们对 MIL-101 MOF 的设计和合成进行了严格审查，评估了其多样化结构的可行性和应用。以前的评论仅限于 MIL-101(Cr)。相反，本研究介绍了不同 MIL-101 金属类似物（包括 Fe、Al、V、Ti、Sc 和 Mn）的合成策略、优点和局限性。此外，我们回顾了关于多变量类型 MIL-101 (MTV-MIL-101) 的文献，其中金属的成对组合参与了框架。我们讨论合成参数如温度、介质 pH、和前体的比例密切影响最终产品的特性。此外，本研究还展示了这些参数的变化对最终框架结构的影响。例如，在最终产品中检测到其他多晶型物，如 MIL-88、MIL-53、MOF-235、MIL-47 和 MIL-67。最后，介绍和讨论了 MIL-101 在吸附、催化、光催化、膜制备、传感器设计和药物输送方面的最新应用。

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Revisiting the MIL-101 metal–organic framework: design, synthesis, modifications, advances, and recent applications

Metal–organic frameworks (MOFs) have expanded into a burgeoning topic in materials science and engineering. Their success mostly stems from the versatility of their structure that can be diversely designed by precise control over the assembly. We conduct a critical review on the design and synthesis of MIL-101 MOFs, assessing the viability and applications of their diversified structures. Previous reviews are limited to the MIL-101(Cr). On the contrary, this study presents the synthesis strategies, the merits, and the limitations of the different MIL-101 metal analogues, including Fe, Al, V, Ti, Sc, and Mn. Furthermore, we review the literature on the multivariate type of MIL-101 (MTV-MIL-101), whereby pairwise combinations of metals are involved in the framework. We discuss how the synthesis parameters such as temperature, medium pH, and ratios of precursors intimately influence the final product characteristics. This study moreover presents the effects of changes in these parameters on the final framework structure. For instance, other polymorphs like MIL-88, MIL-53, MOF-235, MIL-47, and MIL-67 were detected in the final product. Finally, the recent applications of MIL-101 in adsorption, catalysis, photocatalysis, membrane preparation, sensor design, and drug delivery are presented and discussed.

更新日期：2021-10-01

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