Regio- and Stereoselective Syn-Boronation of Terminal Alkynes Catalyzed by Copper Nanospheres on Graphene Nanosheets,ACS Applied Materials & Interfaces

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Regio- and Stereoselective Syn-Boronation of Terminal Alkynes Catalyzed by Copper Nanospheres on Graphene Nanosheets
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2021-09-29 , DOI: 10.1021/acsami.1c11892
Bin Wang ₁ , Lingfeng Gao ₁ , Hua Yang ₂ , Gengxiu Zheng ₁

Affiliation

Evenly distributed copper nanospheres on reduced graphene oxide were prepared and showed high heterogeneous catalytic activity in converting varying terminal alkynes into (E)-β-styrene boronate esters. The excellent catalytic performance was achieved through the synergistic catalysis between Cu nanospheres and rGO. This work not only is a supplement for preparing (E)-β-styrene boronate esters but also provides a way for the rational designing of high-performance graphene-based catalysts. Meanwhile, the advancement of graphene-based nanomaterials will be motivated to promote their applications in the development of green catalytic chemistry.

中文翻译：

石墨烯纳米片上铜纳米球催化末端炔烃的区域选择性和立体选择性合成硼化

在还原氧化石墨烯上制备了均匀分布的铜纳米球，并在将不同的末端炔烃转化为 (E)-β-苯乙烯硼酸酯方面表现出高异质催化活性。优异的催化性能是通过Cu纳米球和rGO之间的协同催化实现的。该工作不仅是制备(E)-β-苯乙烯硼酸酯的补充，而且为高性能石墨烯基催化剂的合理设计提供了一种途径。同时，石墨烯基纳米材料的进步将推动其在绿色催化化学发展中的应用。

更新日期：2021-10-13

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