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Ethane/ethylene separation in a metal-organic framework with shape-matching ethane traps
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2021-09-16 , DOI: 10.1016/j.jssc.2021.122594 Nan Lu 1 , Qiang Gao 1 , Yan-Mei Zhang 1 , Yuan Gao 2 , Lin-Ying Wu 1 , Yao-An Zhao 1 , Li-Zhuang Chen 1
中文翻译:
具有形状匹配的乙烷捕集器的金属有机框架中的乙烷/乙烯分离
更新日期:2021-09-20
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2021-09-16 , DOI: 10.1016/j.jssc.2021.122594 Nan Lu 1 , Qiang Gao 1 , Yan-Mei Zhang 1 , Yuan Gao 2 , Lin-Ying Wu 1 , Yao-An Zhao 1 , Li-Zhuang Chen 1
Affiliation
Ethylene (C2H4) plays an important role in industrial production and energy-efficiency separation C2H4 and C2H6 is one of the important processes for the sustainable development of petrochemical industry. Herein, we chose CPM-35 equipping ethane traps for adsorption separation of C2H6/C2H4. The experiment and computation results show that C2H6 can be priority adsorbed (IAST C2H6/C2H4 selectivity is 1.51 at 298 K and 1 bar) and the purification of C2H4 can be realized by this material.
中文翻译:
具有形状匹配的乙烷捕集器的金属有机框架中的乙烷/乙烯分离
乙烯(C 2 H 4)在工业生产和能效分离中发挥重要作用 C 2 H 4和C 2 H 6是石油化工可持续发展的重要工艺之一。在此,我们选择配备乙烷捕集器的CPM-35进行 C 2 H 6 /C 2 H 4 的吸附分离。实验和计算结果表明,C 2 H 6可以优先吸附(IAST C 2 H 6 /C 2 H 4选择性为 1.51,在 298 K 和 1 bar),C 2 H 4的纯化可以通过这种材料实现。