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High-Throughput Discovery of a Rhombohedral Twelve-Connected Zirconium-Based Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-14 , DOI: 10.1002/anie.202108150 Adam M Tollitt 1 , Rebecca Vismara 1 , Luke M Daniels 1 , Dmytro Antypov 1 , Michael W Gaultois 1 , Alexandros P Katsoulidis 1 , Matthew J Rosseinsky 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-14 , DOI: 10.1002/anie.202108150 Adam M Tollitt 1 , Rebecca Vismara 1 , Luke M Daniels 1 , Dmytro Antypov 1 , Michael W Gaultois 1 , Alexandros P Katsoulidis 1 , Matthew J Rosseinsky 1
Affiliation
The ordered arrangement of terephthalate and fumarate linkers over the fcu net produces a zirconium-based MOF Zr6(BDC)3(Fum)3 with two distinct windows and multiple guest diffusion pathways. This phase is formed by single-step synthesis in a narrow region of the available chemical space, and its identification required a large set of synthetic experiments that were facilitated by automated high-throughput methods.
中文翻译:
高通量发现具有有序对苯二甲酸酯和富马酸酯连接体的菱形十二连接锆基金属有机框架
对苯二甲酸酯和富马酸酯连接体在fcu网上的有序排列产生了具有两个不同窗口和多个客体扩散路径的锆基 MOF Zr 6 (BDC) 3 (Fum) 3 。该相是在可用化学空间的狭窄区域中通过单步合成形成的,其识别需要大量的合成实验,而这些实验是通过自动化高通量方法来促进的。
更新日期:2021-09-14
中文翻译:
高通量发现具有有序对苯二甲酸酯和富马酸酯连接体的菱形十二连接锆基金属有机框架
对苯二甲酸酯和富马酸酯连接体在fcu网上的有序排列产生了具有两个不同窗口和多个客体扩散路径的锆基 MOF Zr 6 (BDC) 3 (Fum) 3 。该相是在可用化学空间的狭窄区域中通过单步合成形成的,其识别需要大量的合成实验,而这些实验是通过自动化高通量方法来促进的。