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Application of Langlois’ reagent (NaSO2CF3) in C–H functionalisation
Chinese Chemical Letters ( IF 9.4 ) Pub Date : 2021-09-09 , DOI: 10.1016/j.cclet.2021.09.005
Jiabin Shen 1 , Jun Xu 1 , Lei He 1 , Chenfeng Liang 1 , Wanmei Li 1
Affiliation  

The process of selectively introducing a CF3 group into an organic molecule using inexpensive, stable, and solid sodium trifluoromethanesulfinate has rapidly advanced in recent years to become an eco-friendly method used by organic chemists to synthesize various natural and bioactive molecules. This review focuses on advances made within the last five years regarding C–H functionalisation, namely thermochemical C(sp2)–H (thio)trifluoromethylations, photochemical C(sp2)–H trifluoromethylations, and electrochemical C(sp2)–H trifluoromethylations, using Langlois’ reagent (NaSO2CF3).



中文翻译:

Langlois 试剂 (NaSO2CF3) 在 C-H 官能化中的应用

近年来,使用廉价、稳定和固体的三氟甲亚磺酸钠选择性地将CF 3基团引入有机分子的过程迅速发展,成为有机化学家用于合成各种天然和生物活性分子的环保方法。本综述重点介绍了过去五年在 C-H 官能化方面取得的进展,即热化学 C(sp 2 )-H (硫代)三氟甲基化、光化学 C(sp 2 )-H 三氟甲基化和电化学 C(sp 2 )-H三氟甲基化,使用 Langlois 试剂 (NaSO 2 CF 3 )。

更新日期:2021-09-09
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