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Strategic Construction of Sulfur-Bridged BODIPY Dimers and Oligomers as Heavy-Atom-Free Photosensitizers
Organic Letters ( IF 4.9 ) Pub Date : 2021-08-31 , DOI: 10.1021/acs.orglett.1c02622 Qingbao Gong 1 , Qinghua Wu 1, 2 , Xing Guo 1 , Wanwan Li 1 , Long Wang 1 , Erhong Hao 1 , Lijuan Jiao 1
Organic Letters ( IF 4.9 ) Pub Date : 2021-08-31 , DOI: 10.1021/acs.orglett.1c02622 Qingbao Gong 1 , Qinghua Wu 1, 2 , Xing Guo 1 , Wanwan Li 1 , Long Wang 1 , Erhong Hao 1 , Lijuan Jiao 1
Affiliation
An efficient strategy for building sulfur-bridged oligo-BODIPYs based on the SNAr reaction is described. These oligo-BODIPYs showed broadband and strong visible-near-infrared (NIR) light absorption, strong intramolecular exciton coupling, and efficient intersystem crossing (ISC). Generation of 1O2 as well as O2•– under irradiation was found to give high reactive oxygen species generation efficiencies for those oligomers.
中文翻译:
硫桥联BODIPY二聚体和低聚物作为无重原子光敏剂的战略构建
描述了一种基于 S N Ar 反应构建硫桥连低聚 BODIPY 的有效策略。这些 oligo-BODIPY 显示出宽带和强可见光近红外 (NIR) 光吸收、强分子内激子耦合和有效的系统间交叉 (ISC)。发现在辐照下生成1 O 2和 O 2 •–可以为这些低聚物提供高活性氧物质生成效率。
更新日期:2021-09-17
中文翻译:
硫桥联BODIPY二聚体和低聚物作为无重原子光敏剂的战略构建
描述了一种基于 S N Ar 反应构建硫桥连低聚 BODIPY 的有效策略。这些 oligo-BODIPY 显示出宽带和强可见光近红外 (NIR) 光吸收、强分子内激子耦合和有效的系统间交叉 (ISC)。发现在辐照下生成1 O 2和 O 2 •–可以为这些低聚物提供高活性氧物质生成效率。