Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries,ACS Applied Materials & Interfaces

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Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2021-08-20 , DOI: 10.1021/acsami.1c10540
Takeshi Shimizu ₁ , Katsuhiro Wakamatsu ₂ , Yasuyuki Yamada _{3,

4,

5} , Yuka Toyoda ₃ , Shigehisa Akine _{6,

7} , Kenji Yoza ₈ , Hirofumi Yoshikawa ₂

Affiliation

μ-Nitrido- and μ-carbido-bridged iron phthalocyanine dimers, when used as cathode-active materials for rechargeable lithium batteries, showed four stable redox waves in cyclic voltammetry studies in solution and a stable discharge capacity of approximately 60 mAh g^–1 after 200 cycles. These results indicate that μ-heteroatom-bridged iron phthalocyanine dimers are good platforms for designing novel phthalocyanine-based electrode-active materials.

中文翻译：

μ-氮化物和μ-碳化物桥连铁酞菁二聚体作为可充电电池阴极活性材料的应用

μ-Nitrido-和μ-碳化-桥连的酞菁铁的二聚体，作为用于锂二次电池阴极活性材料时，在溶液中的循环伏安法研究和大约60毫安g的稳定的放电容量显示出4个稳定的氧化还原波^-1后200 个循环。这些结果表明，μ-杂原子桥接的铁酞菁二聚体是设计新型酞菁基电极活性材料的良好平台。

更新日期：2021-09-01

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