2-Thiazolines: an update on synthetic methods and catalysis,Organic & Biomolecular Chemistry

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2-Thiazolines: an update on synthetic methods and catalysis
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2021-07-29 , DOI: 10.1039/d1ob01180d
Joel I Badillo-Gómez _{1,

2} , Maryse Gouygou ₂ , M Carmen Ortega-Alfaro ₃ , José G López-Cortés ₁

Affiliation

2-Thiazolines are important building blocks in organic synthesis and are of great importance in many areas of chemistry. At the end of the last century, the use of 2-thiazolines increased in a significant way, especially in synthesis and catalysis. This review highlights the synthetic and catalytic value of 2-thiazolines in the last two decades. We will discuss the new synthetic methodologies for obtaining these heterocycles including new schemes for accessing their asymmetric versions. Most of the new catalytic applications include a variety of 2-thiazoline ligands containing diverse donor atoms, which in combination with metals like Pd, Ir, and Cu, among others, exhibit remarkable catalytic performances.

中文翻译：

2-噻唑啉：合成方法和催化的最新进展

2-噻唑啉是有机合成中的重要组成部分，在许多化学领域都非常重要。上世纪末，2-噻唑啉的使用显着增加，特别是在合成和催化方面。这篇综述强调了过去二十年 2-噻唑啉的合成和催化价值。我们将讨论获得这些杂环的新合成方法，包括获得其不对称形式的新方案。大多数新的催化应用包括各种含有不同供体原子的 2-噻唑啉配体，它们与 Pd、Ir 和 Cu 等金属结合，表现出显着的催化性能。

更新日期：2021-08-19

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