Front Cover: Stereoselective Visible-Light Catalyzed Cyclization of Bis(enones): A Viable Approach to the Synthesis of Enantiomerically Enriched Cyclopentane Rings (Eur. J. Org. Chem. 32/2021),European Journal of Organic Chemistry

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Front Cover: Stereoselective Visible-Light Catalyzed Cyclization of Bis(enones): A Viable Approach to the Synthesis of Enantiomerically Enriched Cyclopentane Rings (Eur. J. Org. Chem. 32/2021)
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-08-19 , DOI: 10.1002/ejoc.202100734
Fabrizio Medici ₁ , Simonetta Resta ₁ , Piero Presenti ₁ , Lucia Caruso ₁ , Alessandra Puglisi ₁ , Laura Raimondi ₁ , Sergio Rossi ₁ , Maurizio Benaglia ₁

Affiliation

The Front Cover shows how, like in a modern factory, it is possible to use light to build complex molecules in a continuous process. By exploiting chiral oxazolidinones, an efficient protocol for the in-flow synthesis of enantiomerically enriched functionalized cyclopentane rings has been developed. The stereoselective light-driven cyclization of bis(enones) in a coil photoreactor affords enantio-enriched cyclopentanes. The possibility to perform the cyclization in a 3D-printed mesoreactor was also successfully demonstrated. The authors acknowledge Dr. Sergio Rossi for the Cover picture idea. More information can be found in the Communication by M. Benaglia et al.

中文翻译：

封面：双（烯酮）的立体选择性可见光催化环化：合成对映体富集环戊烷环的可行方法（Eur. J. Org. Chem. 32/2021）

封面展示了如何像在现代工厂中一样，在一个连续的过程中使用光来构建复杂的分子。通过利用手性恶唑烷酮，开发了一种对映体富集的官能化环戊烷环的流入合成的有效方案。双（烯酮）在线圈光反应器中的立体选择性光驱动环化提供了对映体富集的环戊烷。还成功证明了在 3D 打印的介观反应器中进行环化的可能性。作者感谢 Sergio Rossi 博士的封面图片创意。更多信息可以在 M. Benaglia 等人的通讯中找到。

更新日期：2021-08-24

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