Journal of Sol-Gel Science and Technology ( IF 2.3 ) Pub Date : 2021-06-30 , DOI: 10.1007/s10971-020-05454-1 Roya Kavkhani , Mahtab Pourzaki , Abbas Kianvash , Abdollah Hajalilou , Reza Ghaffari Adli
In this study, Mg–Mn–Al ferrite with a chemical composition of Mg0.8Mn0.2Al0.1Fe1.9O4 was synthesized via the sol–gel auto-combustion method. The effects of the sintering time and temperature on the magnetic properties and transmission behaviors were investigated in detail. X-ray diffraction (XRD) results revealed that the powders in the as auto-combusted state were in an amorphous state. Moreover, based on the differential thermal analysis (DTA) curve, the calcination temperature was calculated to be ~900 °C. According to the Archimedes equation, the highest density was obtained for the specimen sintered at 1250 °C for 5 h (94% of the theoretical density). In addition, permagraph results revealed the average magnetic properties of the mentioned samples are as follows: Hc = 7.0 Oe and Ms = 1400 G. According to vector network analyzer (VNA) results, the samples with qualified transmission behaviors showed low scattering parameters in a wide range of frequencies.
中文翻译:
烧结温度和均热时间对纳米晶Mg0.8Mn0.2Al0.1Fe1.9O4磁性能和传输行为的影响
在本研究中,Mg-Mn-Al 铁氧体的化学成分为 Mg 0.8 Mn 0.2 Al 0.1 Fe 1.9 O 4是通过溶胶-凝胶自燃法合成的。详细研究了烧结时间和温度对磁性能和传输行为的影响。X 射线衍射 (XRD) 结果表明,处于自燃状态的粉末处于无定形状态。此外,根据差热分析 (DTA) 曲线,计算出的煅烧温度为 ~900 °C。根据阿基米德方程,在 1250 °C 下烧结 5 小时的试样获得最高密度(理论密度的 94%)。此外,permagraph 结果显示上述样品的平均磁性能如下: H c = 7.0 Oe 和 M s = 1400 G。根据矢量网络分析仪 (VNA) 结果,具有合格传输行为的样品在很宽的频率范围内显示出低散射参数。