Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands,Chemistry - A European Journal

当前位置： X-MOL 学术 › Chem. Eur. J. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2021-07-29 , DOI: 10.1002/chem.202102328
Lewis C H Maddock ₁ , Rebekka Morton ₂ , Alan R Kennedy ₂ , Eva Hevia ₁

Affiliation

Influenced by the large steric demands imposed by the 2,6-diisopropyl-N-(trimethylsilyl)anilide ligand, N(SiMe₃)Dipp, new examples of chemical cooperativity on sodium ferrates have been disclosed. This includes: (a) the chemoselective ferration of pentafluorobenzene by a heteroleptic tris(amido) sodium ferrate; and, (b) the lateral metallation of a N(SiMe₃)Dipp group at one Me of its SiMe₃ substituent when attempting the co-complexation of the sodium and iron (II) single-metal amides.

中文翻译：

含有大块 2,6-二异丙基-N-(三甲基甲硅烷基)苯胺配体的高铁酸钠的横向金属化和再分布反应

受2,6-二异丙基-N-（三甲基甲硅烷基）苯胺配体 N(SiMe ₃ )Dipp强加的大空间位阻要求的影响，高铁酸钠化学协同作用的新实例已被公开。这包括： (a) 杂配三（酰氨基）高铁酸钠对五氟苯的化学选择性高铁反应；(b)在尝试共络合钠和铁 (II) 单金属酰胺时，N(SiMe ₃ )Dipp 基团在其 SiMe ₃取代基的一个 Me 处横向金属化。

更新日期：2021-07-29

点击分享查看原文

点击收藏

阅读更多本刊新发论文