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A 1,8-naphthyridine-based fluorescent chemodosimeter for the rapid detection of Zn2+ and Cu2+.
Organic Letters ( IF 4.9 ) Pub Date : 2008 Nov 20 , DOI: 10.1021/ol8018192
Ming-Ming Yu 1 , Zhan-Xian Li 1 , Liu-He Wei 1 , Dong-Hui Wei 1 , Ming-Sheng Tang 1
Affiliation  

A novel fluorescent chemodosimeter based on 1,8-naphthyridine exhibits high selectivity to Zn(2+) and Cu(2+). When 1-(7-acetamino-1,8-naphthyridyl)-2-(6-diacetaminopyridyl)ethene was mixed with CuCl2, hydrolysis of the acetamino group catalyzed by Cu(2+) complex was first observed. Resulting from coordination and hydrolysis catalyzed by the corresponding complex of Zn(2+) or Cu(2+), the highly effective fluorescent detection of Zn(2+) and Cu(2+) is realized with Zn(2+)-selective dual-emission and Cu(2+)-selective ON-OFF behavior.

中文翻译:

基于1,8-萘啶的荧光化学计量仪,用于快速检测Zn2 +和Cu2 +。

基于1,8-萘啶的新型荧光化学计量器对Zn(2+)和Cu(2+)具有高选择性。当1-(7-乙酰氨基-1,8-萘基)-2-(6-二乙酰氨基吡啶基)乙烯与CuCl2混合时,首先观察到Cu(2+)配合物催化的乙酰氨基水解。通过相应的Zn(2+)或Cu(2+)配合物催化的配位和水解作用,通过Zn(2 +)-选择性实现了Zn(2+)和Cu(2+)的高效荧光检测双发射和Cu(2+)选择性的ON-OFF行为。
更新日期:2017-01-31
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