Dyes and Pigments ( IF 4.1 ) Pub Date : 2021-06-29 , DOI: 10.1016/j.dyepig.2021.109591 Ruidong Wang , Shaoguang Wu , Yanmei Li , Tianzhi Yu , Wenming Su , Yuling Zhao , Yuanying Li , Hongyan Yang
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Four new phenanthroimidazole/N,N-diphenylnaphthalen-2-amine hybrid compounds, 6-(4-(1-(4-(tert-butyl)phenyl)-1H-phenanthro[9,10-d]imidazole-2-yl)phenyl)-N,N-bis(4-methoxyphenyl)naphthalen-2-amine (PPI-NPA-OMe), N,N-bis(4-(tert-butyl)phenyl)-6-(4-(1-(4-(tert-butyl) phenyl)-1H-phenanthro[9,10-d]imidazole-2-yl)phenyl)naphthalen-2-amine (PPI-NPA-t-Bu), 6-(4-(1-(4-(tert-butyl)phenyl)-1H-phenanthro[9,10-d]imidazole-2-yl)phenyl)-N,N-di-p-tolylnaphthalen-2-amine (PPI-NPA-Me) and 4,4'-((6-(4-(1-(4-(tert-butyl)phenyl)-1H-phenanthro[9,10-d] imidazole-2-yl)phenyl)naphthalen-2-yl)azanediyl)dibenzonitrile (PPI-NPA-CN), were successfully synthesized for application in blue light emitting. The thermal stabilities, photophysical and electrochemical properties of the compounds were investigated. Furthermore, the vacuum-processed devices based on these compounds were fabricated, in which the device based on the compound PPI-NPA-OMe exhibited the best electroluminescence performance with a maximum brightness of 12,593 cd/m2, a maximum current efficiency of 9.23 cd/A and a maximum external quantum efficiency (EQE) of 4.92%.
中文翻译:
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不同N , N -二苯基萘-2-胺单元对菲咪唑衍生物光致和电致发光性能的影响
四种新型菲咪唑/ N , N-二苯基萘-2-胺杂化化合物,6-(4-(1-(4-(叔丁基)苯基) -1H-菲[9,10 - d ]咪唑-2-)基)苯基) -N , N-双(4-甲氧基苯基)萘-2-胺 ( PPI-NPA-OMe ), N , N-双(4-(叔丁基)苯基)-6-(4-( 1-(4-(叔丁基)苯基) -1H-菲[9,10 - d ]咪唑-2-基)苯基)萘-2-胺( PPI-NPA-t-Bu ),6-( 4-(1-(4-(叔丁基)苯基)-1 H-菲[9,10-d ]咪唑-2-基)苯基) -N , N-二-对-甲苯基萘-2-胺( PPI-NPA-Me )和4,4'-((6-(4-(1-(4- (叔丁基)苯基) -1H-菲[9,10 - d ]咪唑-2-基)苯基)萘-2-基)氮杂二基)二苯甲腈( PPI-NPA-CN ),成功合成应用于发出蓝光。研究了化合物的热稳定性、光物理和电化学性质。此外,制造了基于这些化合物的真空处理器件,其中基于化合物PPI-NPA-OMe的器件表现出最佳的电致发光性能,最大亮度为 12,593 cd/m 2,最大电流效率为 9.23 cd/A,最大外量子效率(EQE)为 4.92%。