当前位置: X-MOL 学术J. Chem. Res. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Regioselective alkylation of anthrone, 5,5-dimethyl-3-isoxazolidinone and 4-methylquinolone by phase transfer catalysis
Journal of Chemical Research ( IF 1.0 ) Pub Date : 2001-03-01 , DOI: 10.3184/030823401103169171
Eckehard Volker Dehmlow 1 , Jörg Bollhöfer 1 , Gorden Thye 1
Affiliation  

Anthrone (1) can be alkylated selectively to give O-, C,O- or C,C-substituted compounds 2, 4, or 5, respectively. Similarly, 5,5-dimethyl-3-isoxazolidinone (6) and 4-methylquinolone (9) yield N- or O-derivatives 7 and 8 or 10 and 11, respectively. The product ratios can be influenced strongly sometimes by use of different phase transfer catalysts, but the sensitivity of each reaction towards the catalysts is unique.

中文翻译:

通过相转移催化蒽酮、5,5-二甲基-3-异恶唑烷酮和4-甲基喹诺酮的区域选择性烷基化

蒽酮 (1) 可以选择性地烷基化,分别得到 O-、C、O- 或 C、C- 取代的化合物 2、4 或 5。类似地,5,5-二甲基-3-异恶唑烷酮(6)和4-甲基喹诺酮(9)分别产生N-或O-衍生物7和8或10和11。有时使用不同的相转移催化剂会强烈影响产物比率,但每个反应对催化剂的敏感性是独一无二的。
更新日期:2001-03-01
down
wechat
bug