Abstract Two coordination polymers, {[Co(bipmo)(tbip)]·3H2O}n (1) and {[Cd(bipmo)(tbip)]·3H2O}n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2tbip=5-tert-butylisophthalic acid), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of metal-aromatic carboxylate layers, which are pillared by weak interactions to generate a three-dimensional network. The topological structures of 1 and 2 are uninodal nets based on 3-connected nodes with the Schläfli symbol of {63}.

中文翻译：

---

由双(4-(1H-咪唑-1-基)苯基)甲酮和5-(叔丁基)间苯二甲酸酯配体构成的两种配位聚合物的合成和结构表征

摘要 两种配位聚合物，{[Co(bipmo)(tbip)]·3H2O}n (1) 和 {[Cd(bipmo)(tbip)]·3H2O}n (2) (bipmo=bis(4-(1H-咪唑-1-基）苯基）甲酮，H2tbip=5-叔丁基间苯二甲酸），通过溶剂热法合成，并通过元素分析、红外光谱和单晶 X 射线衍射进行结构表征。单晶 X 射线衍射数据的结果表明，1 和 2 的固态结构由金属-芳香族羧酸盐层组成，这些层通过弱相互作用形成三维网络。1 和 2 的拓扑结构是基于 3 个连接节点的单节点网络，Schläfli 符号为 {63}。