Synthesis of 3-Oxosapriparaquinone, a Diterpene fromSalvia prionitisHance,Bulletin of the Chemical Society of Japan

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Synthesis of 3-Oxosapriparaquinone, a Diterpene fromSalvia prionitisHance
Bulletin of the Chemical Society of Japan ( IF 3.3 ) Pub Date : 1995-09-01 , DOI: 10.1246/bcsj.68.2705
Takashi Matsumoto ₁ , Yoshio Takeda ₁ , Kimiko Soh ₁ , Hiroyuki Matsumura ₁ , Sachihiko Imai ₂

Affiliation

12-Acetoxy-5,10-friedo-4,5-seco-abieta-3,5(10),6,8,11,13-hexaene prepared from (+)-dehydroabietic acid, was converted into a natural rearranged abietane-type diterpene, 3-oxosapriparaquinone, via 12-benzoyloxy-3-hydroxy-5,10-friedo-4,5-seco-abieta-5(10),6,8,12-tetraene-11,14-dione by a series of reactions: hydroboration–oxidation, benzoyl peroxide oxidation, Jones oxidation, and alkaline hydrolysis.

中文翻译：

3-Oxosapriparaquinone 的合成，一种来自丹参的二萜

12-Acetoxy-5,10-friedo-4,5-seco-abieta-3,5(10),6,8,11,13-己烯由(+)-脱氢松香酸制备，转化为天然重排松香烷-型二萜, 3-oxosapriparaquinone, via 12-benzoyloxy-3-hydroxy-5,10-friedo-4,5-seco-abieta-5(10),6,8,12-tetraene-11,14-dione一系列反应：硼氢化-氧化、过氧化苯甲酰氧化、琼斯氧化和碱水解。

更新日期：1995-09-01

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