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Reaction of fluoronitrobenzenes with tetramethylguanidine in acetonitrile
Journal of Molecular Structure ( IF 4.0 ) Pub Date : 1999-03-01 , DOI: 10.1016/s0022-2860(98)00758-3
Grzegorz Schroeder , Krystian Eitner , Blazej Gierczyk , Bartosz Rózalski , Bogumil Brzezinski

Abstract Products of the reaction between the three fluorinated nitrobenzenes (2,3,4,6-tetrafluoronitrobenzene, 2,3,4,5-tetrafluoronitrobenzene, pentafluoronitrobenzene) and tetramethylguanidine in acetonitrile were isolated and identified by analytical and spectroscopic methods. As the result of these reactions, ortho and para substituted isomers were formed. In two of the reactions, the para isomers were the main products. The kinetics and the mechanism of these reactions are discussed.

中文翻译:

氟硝基苯与四甲基胍在乙腈中的反应

摘要 通过分析和光谱法分离和鉴定了乙腈中的三种氟化硝基苯(2,3,4,6-四氟硝基苯、2,3,4,5-四氟硝基苯、五氟硝基苯)与四甲基胍反应的产物。作为这些反应的结果,形成了邻位和对位取代的异构体。在两个反应中,对位异构体是主要产物。讨论了这些反应的动力学和机理。
更新日期:1999-03-01
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