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Facile synthesis and spectral characterization of 2, 5-bis (cyclohexylamino)-1, 4-benzoquinone polymorphs from methyl and ethyl protocatechuic aldehydes
Journal of Molecular Structure ( IF 4.0 ) Pub Date : 2017-08-01 , DOI: 10.1016/j.molstruc.2017.03.106
A. Asha , A. Sheena Mohan , S. Suma , M.R. Sudarsanakumar , M.R. Prathapachandra Kurup

Abstract Two polymorphs of 2,5-bis(cyclohexylamino)-1,4-benzoquinone (BCBQI&BCBQII) are synthesized by an efficient alternate method which includes the oxidation of an aromatic aldehyde to benzoquinone moiety followed by its nucleophilic substitution in a single pot. The synthesized polymorphs have been characterized and distinguished by spectral and single crystal X-ray diffraction methods. A possible mechanism for the conversion is also suggested.

中文翻译:

来自甲基和乙基原儿茶醛的 2, 5-双(环己基氨基)-1, 4-苯醌多晶型物的简便合成和光谱表征

摘要 2,5-双(环己基氨基)-1,4-苯醌的两种多晶型物(BCBQI&BCBQII)是通过一种有效的替代方法合成的,该方法包括将芳香醛氧化为苯醌部分,然后在一个锅中进行亲核取代。合成的多晶型物已通过光谱和单晶 X 射线衍射方法进行表征和区分。还建议了一种可能的转换机制。
更新日期:2017-08-01
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