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N,N-DIBROMOBENZENESULFONAMIDE: A USEFUL REGENRABLE REAGENT FOR BROMINATION OF VARIOUS CARBANIONIC SUBSTRATES
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2004-06-01 , DOI: 10.1080/10426500490459768 Mahmood Tajbakhsh , Ardeshir Khazaei , Majid Shabani Mahalli , Ramin Ghorbani Vaghi
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2004-06-01 , DOI: 10.1080/10426500490459768 Mahmood Tajbakhsh , Ardeshir Khazaei , Majid Shabani Mahalli , Ramin Ghorbani Vaghi
N,N-Dibromobenzenesulfonamide(dibromoamine-B), which is prepared easily in high yield, has been employed as effective brominating agent for carbanionic substrates under mild conditions. β-Diketones and β-ketoesters were brominated by this reagent without using any bases. The reagent can be recovered, rebrominated, and reused several times.
中文翻译:
N,N-二溴苯磺酰胺:一种有用的可再生试剂,可用于各种碳负离子底物的溴化
N,N-二溴苯磺酰胺(二溴胺-B)易于高产率制备,已被用作温和条件下碳负离子底物的有效溴化剂。β-二酮和β-酮酯在不使用任何碱的情况下被该试剂溴化。该试剂可以回收、再溴化和重复使用多次。
更新日期:2004-06-01
中文翻译:
N,N-二溴苯磺酰胺:一种有用的可再生试剂,可用于各种碳负离子底物的溴化
N,N-二溴苯磺酰胺(二溴胺-B)易于高产率制备,已被用作温和条件下碳负离子底物的有效溴化剂。β-二酮和β-酮酯在不使用任何碱的情况下被该试剂溴化。该试剂可以回收、再溴化和重复使用多次。