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BENZYTRIPHENYLPHOSPHONIUM BOROHYDRIDE (BTPPB) AS A SELECTIVE REDUCING AGENT FOR REDUCTION OF IMINES, ENAMINES, AND REDUCTIVE AMINATION OF ALDEHYDES WITH PRIMARY AND SECONDRY AMINES IN METHANOL
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2001-03-01 , DOI: 10.1080/10426500108040597
A. R. Hajipour 1 , S. E. Mallakpour 1 , A. R. Najafi 1
Affiliation  

Abstract Benzyltriphenyltriphenylphosphonium borohydride (BTPPB) (1) generated as white solid from benzyltriphenylphosphonium chloride and sodium borohydride is found to be a selective and versatile reducing agent. The reagent in methanol is very useful for reduction of imines, enamines and reductive amination of aldehydes.

中文翻译:

苄基三苯基膦硼氢化物 (BTPPB) 作为一种选择性还原剂,用于在甲醇中还原亚胺、烯胺和醛与伯胺和仲胺的还原胺化

摘要 苄基三苯基三苯基硼氢化鏻 (BTPPB) (1) 以白色固体形式由苄基三苯基氯化鏻和硼氢化钠生成,是一种选择性和通用的还原剂。甲醇中的试剂对于还原亚胺、烯胺和醛的还原胺化非常有用。
更新日期:2001-03-01
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