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The Rhodium Carbenoid Route to 3-Aryl-4-hydroxycoumarins: Synthesis of Derrusnin
Synlett ( IF 1.7 ) Pub Date : 2005-03-23 , DOI: 10.1055/s-2005-864808 Stefano Tollari , Giovanni Palmisano , Luca Goldoni , Giancarlo Cravotto , Andrea Penoni
Synlett ( IF 1.7 ) Pub Date : 2005-03-23 , DOI: 10.1055/s-2005-864808 Stefano Tollari , Giovanni Palmisano , Luca Goldoni , Giancarlo Cravotto , Andrea Penoni
3-Aryl-4-hydroxycoumarins have been obtained in satisfactory yields and selectivity through a Rh(II)-mediated arylation of diazocoumarin. The utility of this approach is demonstrated by synthesis of the natural product derrusnin.
中文翻译:
3-Aryl-4-羟基香豆素的铑卡宾路线:Derrusnin的合成
通过 Rh(II) 介导的重氮香豆素芳基化,以令人满意的产率和选择性获得了 3-Aryl-4-羟基香豆素。这种方法的效用通过天然产物derrusnin的合成得到证明。
更新日期:2005-03-23
中文翻译:
3-Aryl-4-羟基香豆素的铑卡宾路线:Derrusnin的合成
通过 Rh(II) 介导的重氮香豆素芳基化,以令人满意的产率和选择性获得了 3-Aryl-4-羟基香豆素。这种方法的效用通过天然产物derrusnin的合成得到证明。