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Synthesis of Novel Unsymmetrically Bridgehead-substituted Phenylselenobicyclo[1.1.1]pentanes
Synlett ( IF 1.7 ) Pub Date : 2004-01-01 , DOI: 10.1055/s-2004-822882 Roberto Pellicciari , Maura Marinozzi , M. Carmela Fulco , Rosa Rizzo
Synlett ( IF 1.7 ) Pub Date : 2004-01-01 , DOI: 10.1055/s-2004-822882 Roberto Pellicciari , Maura Marinozzi , M. Carmela Fulco , Rosa Rizzo
The synthesis of the two novel unsymmetrical phenylseleno-substituted bicyclo[1.1.1]pentane derivatives, 1-phenylseleno-3-acetylbicyclo[1.1.1]pentane (2) and 1-phenylseleno-3-diethoxy-phosphono bicycle[1.1.1]pentane (3), by radical addition of organoselenium reagents to [1.1.1]propellane is described.
中文翻译:
新型不对称桥头取代苯基硒双环[1.1.1]戊烷的合成
两种新型不对称苯基硒基取代双环[1.1.1]戊烷衍生物1-苯基硒基-3-乙酰基双环[1.1.1]戊烷(2)和1-苯基硒基-3-二乙氧基-膦酰基双环[1.1.1]的合成]戊烷 (3),通过有机硒试剂自由基加成到 [1.1.1] 丙烷进行了描述。
更新日期:2004-01-01
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
新型不对称桥头取代苯基硒双环[1.1.1]戊烷的合成
两种新型不对称苯基硒基取代双环[1.1.1]戊烷衍生物1-苯基硒基-3-乙酰基双环[1.1.1]戊烷(2)和1-苯基硒基-3-二乙氧基-膦酰基双环[1.1.1]的合成]戊烷 (3),通过有机硒试剂自由基加成到 [1.1.1] 丙烷进行了描述。