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(S)-Pyrrolidin-2-ylmethyl-1,2,3-triazolium Salts - Ionic Liquid Supported Organocatalysts for Enantioselective Michael Additions to β-Nitrostyrenes
Synlett ( IF 1.7 ) Pub Date : 2008-07-15 , DOI: 10.1055/s-2008-1078593
Jürgen Liebscher , Zekarias Yacob , Jabbar Shah , Joachim Leistner

(S)-Pyrrolidin-2-ylmethyl-1,2,3-triazolium salts were synthesized as new task-specific ionic liquids via click reaction and alkylation. They serve as excellent recyclable catalysts in enantioselective Michael additions to nitrostyrenes in excess of carbonyl compounds as reactant and as solvent providing high yields and stereoselectivities.

中文翻译:

(S)-Pyrrolidin-2-ylmethyl-1,2,3-triazolium 盐 - 用于对 β-硝基苯乙烯进行对映选择性迈克尔加成的离子液体负载有机催化剂

(S)-Pyrrolidin-2-ylmethyl-1,2,3-triazolium 盐通过点击反应和烷基化合成为新的任务特定离子液体。它们在作为反应物和溶剂提供高产率和立体选择性的硝基苯乙烯对映选择性迈克尔加成反应中用作优异的可回收催化剂,作为反应物和溶剂。
更新日期:2008-07-15
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