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CO2 capturing and in situ conversion at mild condition: Efficient synthesis of methyl phenyl carbonate
Journal of Environmental Chemical Engineering ( IF 7.4 ) Pub Date : 2021-06-15 , DOI: 10.1016/j.jece.2021.105862
Leizhi Zheng , Guoqiang Yang , Xingbang Hu , Zhibing Zhang

The capture and conversion of carbon dioxide (CO2) into useful and valuable chemicals are receiving more and more research interesting. Herein, we designed a new and efficient route to synthesize methyl phenyl carbonate (MPC) via the carbonylation of phenol (PhOH) with CO2 and methanol (CH3OH). PhOH and CH3OH react with 1,8-diazabicyclo-[5.4.0]undec-7-ene (DBU) to form ionic liquids [DBUH][PhO] and [DBUH][CH3O]. The DBU-based ionic liquids exhibited outstanding performance in CO2 capture and in situ conversion at room temperature. The reusability of the system had no obviously change after 6 cycles. This protocol provides a sustainable and environmentally friendly preferential technique for the production of MPC, and extends the chemical utilization of CO2.



中文翻译:

温和条件下的CO 2捕获和原位转化:高效合成碳酸甲基苯基酯

二氧化碳 (CO 2 )的捕获和转化为有用和有价值的化学品正受到越来越多的研究。在此,我们设计了一种新的高效路线,通过苯酚 (PhOH) 与 CO 2和甲醇 (CH 3 OH)的羰基化合成碳酸甲基苯酯 (MPC )。PhOH 和 CH 3 OH 与 1,8-二氮杂双环-[5.4.0] undec-7-ene (DBU) 反应形成离子液体 [DBUH][PhO] 和 [DBUH][CH 3 O]。基于 DBU 的离子液体在 CO 2 中表现出优异的性能在室温下捕获和原位转化。6个循环后系统的可重用性无明显变化。该协议为 MPC 的生产提供了一种可持续和环保的优惠技术,并扩展了 CO 2的化学利用。

更新日期:2021-06-24
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