Recent advances in acyl radical enabled reactions between aldehydes and alkenes,Chemical Communications

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Recent advances in acyl radical enabled reactions between aldehydes and alkenes
Chemical Communications ( IF 4.3 ) Pub Date : 2021-5-25 , DOI: 10.1039/d1cc02112e
Yi-Lin Liu ₁ , Yue-Jun Ouyang ₁ , Hongxing Zheng ₂ , Hongxin Liu ₃ , Wen-Ting Wei ₄

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Radical-mediated functionalization of alkenes has been emerging as an elegant and straightforward protocol to increase molecule complexity. Moreover, the abstraction of a hydrogen atom from aldehydes to afford acyl radicals has evolved as a rising star due to its high atom-economy and the ready availability of aldehydes. Considering the great influence and synthetic potential of acyl radical enabled reactions between aldehydes and alkenes, we provide a summary of the state of the art in this field with a specific emphasis on the working models and corresponding mechanisms. The discussion is divided according to the kind of alkenes and reaction type.

中文翻译：

酰基自由基的最新进展使醛和烯烃之间的反应成为可能

烯烃的自由基介导的功能化已经成为一种优雅而直接的方案，以增加分子的复杂性。此外，由于其高原子经济性和醛的易得性，从醛中提取氢原子以提供酰基自由基已成为一颗冉冉升起的新星。考虑到醛与烯烃之间的酰基自由基反应的巨大影响和合成潜力，我们总结了该领域的最新技术，并特别强调了工作模型和相应的机制。讨论根据烯烃的种类和反应类型进行划分。

更新日期：2021-06-11

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