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Novel Chromeno[2,3-b]pyridines from Basic Rearrangement of 4-Oxo-chromene-3-carbonitrile
Synthetic Communications ( IF 1.8 ) Pub Date : 2009-09-04 , DOI: 10.1080/00397910902788141 Magdy A. Ibrahim 1
Synthetic Communications ( IF 1.8 ) Pub Date : 2009-09-04 , DOI: 10.1080/00397910902788141 Magdy A. Ibrahim 1
Affiliation
Abstract A new series of 2,3-disubstituted-5-oxochromeno[2,3-b]pyridine derivatives has been obtained throughout a 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed reaction of 4-oxo-4H-chromene-3-carbonitrile with various active methyl and methylene compounds. The Friedländer reaction of 2-amino-4-oxo-4H-chromene-3-carboxaldehyde with the same active methyl and methylene compounds led to the identical products, suggesting that basic catalyzed ring rearrangement took place during the course of reaction.
中文翻译:
来自 4-Oxo-chromene-3-carbonitrile 基本重排的新型 Chromeno[2,3-b] 吡啶
摘要 通过 1,8-二氮杂双环[5.4.0]十一碳-7-烯 (DBU) 催化反应,获得了一系列新的 2,3-二取代-5-氧代色基[2,3-b]吡啶衍生物。 4-oxo-4H-chromene-3-carbonitrile 与各种活性甲基和亚甲基化合物。2-amino-4-oxo-4H-chromene-3-carboxaldehyde 与相同的活性甲基和亚甲基化合物的 Friedländer 反应产生相同的产物,表明在反应过程中发生了碱性催化的环重排。
更新日期:2009-09-04
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
来自 4-Oxo-chromene-3-carbonitrile 基本重排的新型 Chromeno[2,3-b] 吡啶
摘要 通过 1,8-二氮杂双环[5.4.0]十一碳-7-烯 (DBU) 催化反应,获得了一系列新的 2,3-二取代-5-氧代色基[2,3-b]吡啶衍生物。 4-oxo-4H-chromene-3-carbonitrile 与各种活性甲基和亚甲基化合物。2-amino-4-oxo-4H-chromene-3-carboxaldehyde 与相同的活性甲基和亚甲基化合物的 Friedländer 反应产生相同的产物,表明在反应过程中发生了碱性催化的环重排。