Copper-Phosphine Mediated Oxidative Phosphorylation of Aromatic Amines and P(OR)3 under Aerobic Conditions,European Journal of Organic Chemistry

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Copper-Phosphine Mediated Oxidative Phosphorylation of Aromatic Amines and P(OR)3 under Aerobic Conditions
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-05-27 , DOI: 10.1002/ejoc.202100550
Shihaozhi Wang ₁ , Shidi Ma ₁ , Jiale Yang ₁ , Wenshuang Li ₁ , Dianjun Li ₁ , Jinhui Yang ₁

Affiliation

A copper-phosphine system was developed to promote the formation of α-aminophosphonates and phosphoramides from various aromatic amines and trialkyl phosphites under aerobic conditions. Importantly, this method could be applied not only to the synthesis of α-aminophosphonates (C−P bonds) but also to produce phosphoramides (N−P bonds). This strategy provided a convenient and efficient method for the synthesis of phosphorous compounds.

中文翻译：

铜-膦介导的芳香胺和 P(OR)3 在有氧条件下的氧化磷酸化

开发了铜-膦系统以促进在有氧条件下由各种芳香胺和亚磷酸三烷基酯形成 α-氨基膦酸酯和磷酰胺。重要的是，这种方法不仅可以用于合成 α-氨基膦酸酯（CP 键），还可以用于生产磷酰胺（NP 键）。该策略为磷化合物的合成提供了一种方便有效的方法。

更新日期：2021-06-13

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