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Carbon-coated MoSe2/Mo2CTx (MXene) heterostructure for efficient hydrogen evolution
Materials Science and Engineering: B ( IF 3.9 ) Pub Date : 2021-05-26 , DOI: 10.1016/j.mseb.2021.115239
Yuanbo Tan , Mingjie Yi , Zhenye Zhu , Xueting Zhang , Ke Qin , Jiaheng Zhang , Rongshu Zhu

Herein, a mesh carbon-coated MoSe2/Mo2CTx hybrid material (MoSe2/Mo2CTx@C) is proposed as an effective catalyst for electrochemical hydrogen evolution reaction (HER). On one hand, the highly conductive Mo2CTx substrate enhanced charge transfer ability and effectively prevented the agglomeration of MoSe2 nanosheets to expose abundant active sites. On the other hand, the carbon coating layer further improved the conductivity and effectively prevented Mo2CTx from being oxidized in the environment. Consequently, the unique MoSe2/Mo2CTx@C hybrid material exhibited excellent HER performance. Specifically, the MoSe2/Mo2CTx@C catalyst only required an overpotential of 108.3 mV to reach a current density of 10 mA cm−2 and displayed excellent durability under long-term cycling in acidic solution. This research highlights the potential applications of MXene-based composite materials in the energy field.



中文翻译:

碳包覆的MoSe 2 / Mo 2 CT x(MXene)异质结构可有效释放氢气

在此,提出了一种网状碳包覆的MoSe 2 / Mo 2 CT x杂化材料(MoSe 2 / Mo 2 CT x @C)作为电化学放氢反应(HER)的有效催化剂。一方面,高导电性的Mo 2 CT x衬底增强了电荷转移能力,并有效地防止了MoSe 2纳米片的团聚,从而暴露出大量的活性位点。另一方面,碳涂层进一步改善了导电性并且有效地防止了Mo 2 CT x在环境中被氧化。因此,独特的MoSe 2 / Mo2 CT x @C杂化材料表现出出色的HER性能。具体地,MoSe 2 / Mo 2 CT x C催化剂仅需要108.3 mV的过电势即可达到10 mA cm -2的电流密度,并且在酸性溶液中长期循环下显示出优异的耐久性。这项研究突出了基于MXene的复合材料在能源领域的潜在应用。

更新日期:2021-05-26
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