Journal of Energy Chemistry ( IF 14.0 ) Pub Date : 2021-05-26 , DOI: 10.1016/j.jechem.2021.05.021
Fangying Zheng , Zeyu Wei , Huicong Xia , Yunchuan Tu , Xiangyu Meng , Kaixin Zhu , Jiao Zhao , Yimin Zhu , Jianan Zhang , Yan Yang , Dehui Deng
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Molybdenum sulfide (MoS2) with well-designed porous structure has the potential to be great electrode materials in sodium-ion batteries due to its high theoretical capacity and abundant resource, however, hindered by its intrinsic low conductivity and stability. Herein, MoS2 with 3D macroporous foam structure and high conductivity was obtained through SiO2 templates and integrated with carbon paper (3D F-MoS2/CP). It has showed superior specific capacity (225 mA h g−1, 0.4–3 V) and cycling stability (1000 cycles) at high rate (2000 mA g−1), with a low decay rate (0.033% per cycle) in sodium-ion batteries. The excellent electrochemical performance may originate from its unique integrated structure: 3D MoS2 macropores providing high surface area and abundant transfer channels while carbon paper enhancing the conductivity of MoS2 and avoiding unnecessary side reactions brought by binder addition.
中文翻译:

3D MoS 2泡沫与碳纸集成作为高性能钠离子电池的无粘合剂负极
具有精心设计的多孔结构的硫化钼(MoS 2)由于其高理论容量和丰富的资源而具有成为钠离子电池电极材料的潜力,但其固有的低电导率和稳定性受到阻碍。在此,的MoS 2的三维大孔的泡沫结构和高导电性的SiO通过获得2模板和与碳纸(3D F-集成的MoS 2 / CP)。它在高倍率(2000 mA h g -1,0.4-3 V)和循环稳定性(1000 次循环)下表现出优异的比容量(225 mA h g -1),在钠离子电池中具有低衰减率(每个循环 0.033%)。优异的电化学性能可能源于其独特的集成结构:3D MoS 2大孔提供高表面积和丰富的传输通道,同时碳纸增强了MoS 2的导电性并避免了添加粘合剂带来的不必要的副反应。