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Inorganic Synthesis Based on Reactions of Ionic Liquids and Deep Eutectic Solvents
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-05-25 , DOI: 10.1002/anie.202104035
Tao Zhang 1, 2 , Thomas Doert 3 , Hui Wang 1, 2 , Suojiang Zhang 1, 2 , Michael Ruck 3, 4
Affiliation  

Ionic liquids and deep eutectic solvents are of growing interest as solvents for the resource-efficient synthesis of inorganic materials. This Review covers chemical reactions of various deep eutectic solvents and types of ionic liquids, including metal-containing ionic liquids, [BF4]- or [PF6]-based ionic liquids, basic ionic liquids, and chalcogen-containing ionic liquids. Cases in which cations, anions, or both are incorporated into the final products are also included. The purpose of this Review is to raise caution about the chemical reactivity of ionic liquids and deep eutectic solvents and to establish a guide for their proper use.

中文翻译:

基于离子液体和低共熔溶剂反应的无机合成

离子液体和深共熔溶剂作为无机材料资源高效合成的溶剂越来越受到关注。本综述涵盖各种低共熔溶剂和离子液体类型的化学反应,包括含金属离子液体、[BF 4 ] - - 或 [PF 6 ] -离子液体、碱性离子液体和含硫属元素离子液体. 还包括将阳离子、阴离子或两者结合到最终产品中的情况。本综述的目的是提醒人们注意离子液体和低共熔溶剂的化学反应性,并为其正确使用建立指南。
更新日期:2021-05-25
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